| 氢键和供体－受体相互作用驱动的酰肼异体二聚体组装 |
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| 引用本文： | 冯代军,王鹏,李小强,黎占亭. 氢键和供体－受体相互作用驱动的酰肼异体二聚体组装[J]. 中国化学, 2006, 24(9): 1200-1208 |
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| 作者姓名： | 冯代军 王鹏 李小强 黎占亭 |
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| 作者单位： | Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| 基金项目： | Project supportecl by the National Natural Science Foundation of China （Nos. 20321202. 20332040. 20425208）. Dedicated to Professor Xikui Jiang on the occasion of his 80th birthday. |
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| 摘 要： | A new series of hydrogen bonding-driven heterodimers have been self-assembled in chloroform from hydrazide-based monomers. Additional intermolecular donor-acceptor interaction between the electron-rich bis（p-phenylene）-34-crown-10 unit and the electron-deficient naphthalene diimide unit has been utilized to increase the stability of the dimmers, and pronounced cooperativity of the two discrete non-covalent forces to stabilize the dimer has been revealed by the quantitative ^1H （2D） NMR and UV-Vis experiments.
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| 关 键 词： | 酰肼 异质二聚物 自组装 氢键结合 供体-受体相互作用 |
| 收稿时间： | 2006-01-11 |
| 修稿时间： | 2006-01-112006-05-16 |
Self-assembly of Hydrazide-based Heterodimers Driven by Hydrogen Bonding and Donor-Acceptor Interaction |
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| FENG Dai-Jun, WANG Peng, LI Xiao-Qiang, LI Zhan-Ting. Self-assembly of Hydrazide-based Heterodimers Driven by Hydrogen Bonding and Donor-Acceptor Interaction[J]. Chinese Journal of Chemistry, 2006, 24(9): 1200-1208 |
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| Authors: | FENG Dai-Jun WANG Peng LI Xiao-Qiang LI Zhan-Ting |
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| Affiliation: | Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | |
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| Keywords: | hydrazide heterodimer self-assembly hydrogen bonding donor-acceptor interaction |
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