Recent advances in the use of phosphorus-centered radicals in organic chemistry |
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Authors: | Leca Dominique Fensterbank Louis Lacôte Emmanuel Malacria Max |
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Affiliation: | Université Pierre et Marie Curie, Institut de chimie moléculaire (FR 2769), Laboratoire de chimie organique (UMR CNRS 7611), C. 229, 4 place Jussieu, 75005, Paris, France. |
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Abstract: | This tutorial review aims at presenting recent contributions dealing with organic chemistry of organophosphorus radicals. The first part briefly lays out the physical organic background of such intermediates. In a second part the use of organophosphorus radicals possessing a P-H bond that can undergo homolytic cleavage as alternative mediators is detailed. The third part is focused on radical additions of phosphorus-centered radicals to unsaturated compounds, an old reaction that is being rejuvenated. Lastly, radical eliminations of phosphorus-centered radical are introduced in the fourth part. Most of the latter are relatively novel reactions, and have never been reviewed previously. |
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