| A Novel Organic—Inorganic Complex：Synthesis and Crystal Structure of [Ca（DMSO）5（H2O）]2 SiMo12O40 |
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| 引用本文： | Jing Ping WANG,Qiang WU,Jing Yang NIU* School of Chemistry and Chemical Engineering,Henan University,Kaifeng 475001. A Novel Organic—Inorganic Complex：Synthesis and Crystal Structure of [Ca（DMSO）5（H2O）]2 SiMo12O40[J]. 中国化学快报, 2002, 13(9): 915-918 |
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| 作者姓名： | Jing Ping WANG Qiang WU Jing Yang NIU* School of Chemistry and Chemical Engineering Henan University Kaifeng 475001 |
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| 作者单位： | Jing Ping WANG，Qiang WU，Jing Yang NIU* School of Chemistry and Chemical Engineering，Henan University，Kaifeng 475001 |
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| 摘 要： | It is becoming a focus to synthesize and assemble organic-inorganic materials, especially, to synthesize charge-transfer complexes formed by polyoxometalate and organic donors. They have attracted much attention because such complexes are active in their electric, magnetic and optic properties1-4, many investigations about them have been done and some crystal structures of them were reported5-6. But, the disadvantage of these crystals is instability at room temperature. According to the view…
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| 关 键 词： | 有机－无机络合物 合成 晶体结构 钼 硅 钙络合物 二甲基亚砜配位基 |
A Novel Organic-Inorganic Complex: Synthesis and Crystal Structure of [Ca(DMSO)5(H2O)]2SiMo12O40 |
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| Jing Ping WANG,Qiang wu,Jing Yang NIU. A Novel Organic-Inorganic Complex: Synthesis and Crystal Structure of [Ca(DMSO)5(H2O)]2SiMo12O40[J]. Chinese Chemical Letters, 2002, 13(9): 915-918 |
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| Authors: | Jing Ping WANG Qiang wu Jing Yang NIU |
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| Abstract: | A novel organic-inorganic complex [Ca(DMSO)5(H2O)]2SiMo12O40 was synthesized from CaCl2, DMSO and H4SiMo12O40nH2O in mixed solvent of acetonitrile and water. Its structure was characterized with elemental analysis, IR and X-ray diffraction analysis. |
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| Keywords: | Synthesis crystal structure organic-inorganic complex. |
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