Crystal structure of a new precursor of radical-clock based on the norbornenyl framework |
| |
Authors: | C. Bernard-Henriet J. Jaud A. Baldy J. M. Mattalia M. Chanon |
| |
Affiliation: | 1. Laboratoire AM3, URA CNRS 1411, Faculté des Sciences de Saint-Jér?me, Case 561, F-13397, Marseille Cedex 20, France 2. Cemes-loe CNRS, 29 rue Jeanne Marvig, BP 4347, F-31055, Toulouse Cedex 4, France
|
| |
Abstract: | The crystal of 5-phenyl-2-endo-(propane-2-sulfonyl)-bicyclo[2-2-1]hept-5-ene-2-carbonitrile1, a new radical-clock is described. The structure has confirmed the configuration for the positions of the phenyl and sulfonyl groups. In the crystal, the radical precursor carbon atom of the propane group is not neighbouring with the double bond of the norbornene. Nevertheless, in solution, it may be expected an ideal conformation with a short intergroup distance leading to a cyclization process. Crystal data: C17H19NO2S, triclinic, space group P−1,a=6.567 (3),b=10.407(5),c=12.610(6), α=110.48(2), β=95.88(2), λ=102.67(3). |
| |
Keywords: | Crystal structure radical-clock distance between reactive centers |
本文献已被 SpringerLink 等数据库收录! |
|