|
|||||
|
|
Komplexkatalyse : XXII. Elektronenstoss-induzierter zerfall der dimeren η-allylnickel(II)-halogenide (C3H5NiX)2 (X = Cl, Br, I) |
|
| Authors: | Norbert Stransky Rainer Herzschuh |
| Institution: | Karl-Marx-Universität Leipzig, Sektion Chemie, DDR-7010 Leipzig, Liebigstrasse 18 D.D.R. Technische Hochschule “Carl Schorlemmer” Leuna-Merseburg, Sektion Chemie, DDR-4200 Merseburg, Otto-Nuschke-Strasse D.D.R. |
| Abstract: | The EI-mass spectra of the dimeric η3-allylnickel(II) halides (C3H5NiX)2 (X = Cl, Br, I) were recorded. Besides the successive splitting-off of the C3H5 groups and the elimination of C3H5X, the formation of NiX2 leading to (C3H5)2Ni is the predominating fragmentation path. Cleavage of the dimeric structure is observed only in the case where X = I. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |