| N-乙烯基咪唑鎓盐聚合物的合成、表征及其电化学性能 |
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| 引用本文： | 刘小平,唐有根,马李思思,王海波. N-乙烯基咪唑鎓盐聚合物的合成、表征及其电化学性能[J]. 化学研究, 2008, 19(3): 42-44 |
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| 作者姓名： | 刘小平 唐有根 马李思思 王海波 |
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| 作者单位： | 中南大学,化学化工学院,化学电源与材料研究所,湖南,长沙,410083 |
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| 摘 要： | 以N-乙烯基咪唑、溴丁烷、丙烯酸乙酯为原料，合成了聚溴化N-乙烯基-N’-丁基咪唑以及溴化N-乙烯基-N’-丁基咪唑丽烯酸乙酯共聚物，通过红外、核磁、元素分析对其结构进行了表征．采用阴极极化曲线测试了其电化学性能，结果表明两者对铜离子阴极还原产生了极大的极化作用．
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| 关 键 词： | 自由基聚合反应 N-乙烯基咪唑 共聚物 丙烯酸乙酯 |
Synthesis of Poly(N-vinylimidazole salt) and Characterization of Its Structure and Electrochemical Property |
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| LIU Xiao-ping,TANG You-gen,MA Li-sisi,WANG Hai-bo. Synthesis of Poly(N-vinylimidazole salt) and Characterization of Its Structure and Electrochemical Property[J]. Chemical Research, 2008, 19(3): 42-44 |
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| Authors: | LIU Xiao-ping TANG You-gen MA Li-sisi WANG Hai-bo |
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| Affiliation: | ( Chemical Power and Material Institute, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan, China) |
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| Abstract: | Poly(N-vinyl-N'-butylimidazoliniumbromide) and poly(N-vinyl-N'-butylimidazoliniumbromide-co-ethyl acrylate) were synthesized from N-vinylimidazole,ethyl acrylate and n-butyl bromide.The structures of the products were characterized by IR,1H NMR,elemental analysis.Moreover,the electrochemical properties were measured by cathodic polarization.The results indicate that the compounds can promote copper ion into polarization greatly. |
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| Keywords: | free radical polymerization N-vinylimidazole copolymer ethyl acrylate |
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