| 氟烷基叠氮化合物和缺电子烯烃反应的研究 |
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| 引用本文： | SUN Qing-Rui,CHEN Zi-Xian,LI Shan,WU Yong-Ming,TIAN Wei-Sheng,. 氟烷基叠氮化合物和缺电子烯烃反应的研究[J]. 中国化学, 2008, 26(10): 1887-1892. DOI: 10.1002/cjoc.200890339 |
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| 作者姓名： | SUN Qing-Rui CHEN Zi-Xian LI Shan WU Yong-Ming TIAN Wei-Sheng |
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| 作者单位： | a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, ; Chinese Academy of Sciences, Shanghai 200032, China ;b Shanghai Normal University, Life and Environment Science College, Shanghai 200234, China ;c Department of Chemistry, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China ; |
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| 摘 要： | 本论文研究了氟烷基叠氮化合物和缺电子烯烃的1,3-偶极反应, 合成了一系列含氟烷基三唑啉和氟烷基吡唑啉类化合物, 并提出了一个通过开环和以重氮化合物为中间体的反应机理.
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| 关 键 词： | 1 3-dipolar cycloaddition fluoroalkylazide fluoroalkylated triazoline fluoroalkylated pyrazoline |
| 收稿时间： | 2008-04-15 |
| 修稿时间： | 2008-05-26 |
Studies on the Reactions of Fluoroalkylazides with Electron‐deficient Alkenes |
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| Qing‐Rui SUN,Zi‐Xian CHEN,Shan LI,Yong‐Ming WU,Wei‐Sheng TIAN. Studies on the Reactions of Fluoroalkylazides with Electron‐deficient Alkenes[J]. Chinese Journal of Chemistry, 2008, 26(10): 1887-1892. DOI: 10.1002/cjoc.200890339 |
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| Authors: | Qing‐Rui SUN Zi‐Xian CHEN Shan LI Yong‐Ming WU Wei‐Sheng TIAN |
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| Affiliation: | 1. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China;2. Shanghai Normal University, Life and Environment Science College, Shanghai 200234, China;3. Department of Chemistry, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China;4. Tel.: 0086‐021‐54925190;5. Fax: 0086‐021‐64166128 |
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| Abstract: | The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed. |
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| Keywords: | 1,3‐dipolar cycloaddition fluoroalkylazide fluoroalkylated triazoline fluoroalkylated pyrazoline |
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