Heteroaryl manganese reagents: direct preparation and reactivity studies |
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| Authors: | Reuben D. Rieke YoungSung Suh |
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| Affiliation: | a Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE 68588-0304, USA
b Rieke Metals Inc., 1001 Kingbird Rd, Lincoln, NE 68521, USA |
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| Abstract: | Direct preparation of various heteroaryl manganese reagents was performed by using highly active manganese (Mn∗) and heteroaryl halides. The resulting organomanganese reagents were coupled with electrophiles such as aryl halides, vinyl halides, and benzoyl chlorides under mild reaction conditions. The corresponding coupling products were obtained in good yields. |
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