BINOL-derived N-phosphino sulfoximines as ligands for asymmetric catalysis |
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| Authors: | Manfred T. Reetz Oleg G. Bondarev Hans-Joachim Gais Carsten Bolm |
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| Affiliation: | a Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim/Ruhr, Germany
b Institut für Organische Chemie der Rheinisch-Westfälische Hochschule (RWTH) Aachen, Landoltweg 1, 52056 Aachen, Germany |
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| Abstract: | BINOL-derived N-phosphino sulfoximines have been prepared for the first time and tested as ligands in asymmetric transition metal catalysis. Up to 99% ee was achieved in the Rh-catalyzed asymmetric hydrogenation of functionalized olefins and up to 66% ee in the Pd-catalyzed allylic alkylation. |
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| Keywords: | Asymmetric reactions N-Phosphino sulfoximines Rhodium Hydrogenation Allylation |
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