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A new method for the generation of azoalkenes from ketohydrazones and its application to the synthesis of tetrahydropyridazine derivatives
Authors:SL Gaonkar
Institution:Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India
Abstract:The reaction of ketohydrazones containing an α-methylene group with chloramine-T followed by treatment with triethylamine leads to the formation of azoalkenes via an α-chloroazo-compound, which can react intermolecularly and in situ with olefinic compounds to produce tetrahydropyridazine derivatives in good yield.
Keywords:Chloramine-T  Tetrahydropyridazine  Azoalkenes
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