A new method for the generation of azoalkenes from ketohydrazones and its application to the synthesis of tetrahydropyridazine derivatives |
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Authors: | SL Gaonkar |
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Institution: | Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India |
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Abstract: | The reaction of ketohydrazones containing an α-methylene group with chloramine-T followed by treatment with triethylamine leads to the formation of azoalkenes via an α-chloroazo-compound, which can react intermolecularly and in situ with olefinic compounds to produce tetrahydropyridazine derivatives in good yield. |
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Keywords: | Chloramine-T Tetrahydropyridazine Azoalkenes |
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