Synthesis and thermal modulation of the fluorescence of a pyrene-arylmaleimide dyad and its Diels-Alder adduct |
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Authors: | Zhuo Wang Deqing Zhang Daoben Zhu |
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Institution: | a The Key Laboratory of Organic Solids, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China b Graduate School, Chinese Academy of Sciences, Beijing 100080, China |
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Abstract: | The fluorescence of a pyrene-arylmaleimide dyad and its Diels-Alder adduct can be thermally modulated through reversible Diels-Alder reaction of arylmaleimide unit with furan. Moreover, the fluorescence intensities of the Diels-Alder adduct of dyad 1 with furan vary linearly with the temperatures of the corresponding solutions, demonstrating that these molecules are interesting compounds for studies of fluorescent molecular thermometers. |
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