The effect of phenolates in the (salen)Mn-catalyzed epoxidation reactions |
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| Authors: | Christian Linde Björn Åkermark |
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| Institution: | a AstraZeneca, R&D, SE-151 85 Södertälje, Sweden
b Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden |
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| Abstract: | By addition of 2,4,6-tri-tert-butylphenolate in the Mn(salen) catalyzed epoxidation of cis-alkenes with iodosobenzene, essentially pure trans-epoxides can be obtained. |
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| Keywords: | Asymmetric catalysis Manganese Schiff bases Oxygenations Reaction mechanisms |
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