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Oxidation/reduction interconversion of thiols and disulfides using hydrogen and oxygen catalyzed by a rhodium complex |
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| Authors: | Mieko Arisawa |
| Institution: | Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Aoba, Sendai 980-8578, Japan |
| Abstract: | RhH(PPh3)4 catalyzes reduction of disulfides to thiols by hydrogen and RhH(PPh3)4/1,4-bis(diphenylphosphino)butane (dppb) catalyzes oxidation of thiols to disulfides by oxygen. |
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