Catalytic enantioselective allylation of aldehydes via a moisture-tolerant chiral BINOL-In(III) complex |
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| Authors: | Yong-Chua Teo Teck-Peng Loh |
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| Affiliation: | a Department of Chemistry, 3 Science Drive 3, National University of Singapore, Singapore 117543, Singapore
b Division of Chemistry and Biological Chemistry, Nanyang Technological University, Singapore 637616, Singapore |
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| Abstract: | A moisture-tolerant chiral indium complex has been developed to effect good enantioselectivities in the addition of allyltributylstannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in both moderate to good yields and high enantioselectivities (up to 86% ee). |
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| Keywords: | Moisture-tolerant Catalytic Chiral indium complex Enantioselective allylation |
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