Lithium perchlorate-catalyzed regioselective ring-opening of aziridines with potassium thiocyanate |
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| Authors: | JS Yadav BV Subba Reddy B Jyothirmai MSR Murty |
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| Institution: | Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | Aziridines react smoothly with potassium thiocyanate in the presence of a catalytic amount of lithium perchlorate in acetonitrile under mild reaction conditions to afford the corresponding β-aminothiocyanates in high yields and with high regioselectivity. The combination of lithium perchlorate and acetonitrile provides a convenient catalytic medium to perform the reactions under neutral conditions. |
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| Keywords: | Lithium perchlorate Aziridines Potassium thiocyanate β-Aminothiocyanates |
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