The exclusive formation of cyclopentenones from molybdenum hexacarbonyl-catalyzed Pauson-Khand reactions of 5-allenyl-1-ynes |
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| Authors: | Arun Kumar Gupta |
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| Affiliation: | Department of Chemistry, Hanyang University, Sungdong-Gu, Seoul 133-791, North Korea |
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| Abstract: | The exclusive formation of cyclopentenones (via path B) was observed in molybdenum hexacarbonyl (10 mol %) catalyzed Pauson-Khand reactions of 1,6-allenynes under 1 atm of CO (balloon) without any substitutent effect. |
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| Keywords: | Molybdenum hexacarbonyl 1,6-Allenynes Pauson-Khand reaction Cyclopentenones |
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