Electrochemically induced dethreading of a 2-pseudorotaxane based on the 1,2-bis(4,4′-pyridinium)ethane/24-crown-8 ether motif |
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Authors: | Brian Gorodetsky |
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Institution: | Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, BC, Canada V5A 1S6 |
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Abstract: | Reversible electrochemical regulation of dethreading and rethreading of a 2-pseudorotaxane complex composed of a dibenzo-24-crown-8 ‘wheel’ noncovalently bound to the ethyl bridge of a bis-viologen ‘axle’ is demonstrated by cyclic voltammetry. |
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Keywords: | Rotaxane Dethreading Switching |
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