Palladium-catalyzed and organozinc-promoted synthesis of dienes from allylic esters possessing an acyloxy or alkoxy group |
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| Authors: | Hatsuhiko Hattori |
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| Affiliation: | Department of Biomolecular Engineering, Tokyo Institute of Technology, Box B-52, Nagatsuta-cho 4259, Midori-ku, Yokohama 226-8501, Japan |
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| Abstract: | Organozinc and a Pd catalyst promoted formation of dienes from allylic esters possessing a leaving group such as acyloxy and alkoxy groups next to the allyl moiety. The reaction proceeded with high regio- and stereoselectivity when applied to secondary allylic substrates. |
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| Keywords: | Palladium catalyst Organozinc Diene p-Allylpalladium |
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