Free radical ring expansion and chain extension of 1,3-diketones |
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| Authors: | Xue-Jun Mu Zhi-Tao Wang |
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| Affiliation: | a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, 1 Shizi Street, Suzhou, Jiangsu 215006, China
b Fluorous Technologies, Inc., University of Pittsburgh Applied Research Center, 970 William Pitt Way, Pittsburgh, PA 15238, USA |
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| Abstract: | Free radical-promoted one carbon ring expansion and chain extension of 1,3-diketones including 1,3-diarylpropane-1,3-diones and 2-aroyl-3,4-dihydro-2H-naphalen-1-one to generate corresponding 1,4-diketones are described. |
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| Keywords: | 1,3-Diketones 1,4-Diketones Chain extension Ring expansion Radical reaction Tributyltin hydride |
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