A facile photoinduced iodoperfluoroalkylation of dienes, diynes, and enynes with perfluoroalkyl iodides via selective radical cyclization |
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| Authors: | Kaname Tsuchii Nagisa Kamada Akihiro Nomoto |
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| Affiliation: | a Department of Chemistry, Faculty of Science, Nara Women’s University, Kitauoyanishi-machi, Nara 630-8506, Japan
b Department of Applied Chemistry, Faculty of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka 599-8531, Japan |
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| Abstract: | Perfluoroalkyl iodides serve as excellent mediators for the radical cyclization of dienes, diynes, and enynes upon irradiation with near-UV light, providing the corresponding iodoperfluoroalkylated cyclic compounds in moderate to good yields. |
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