Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids |
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| Authors: | Yong-Chua Teo Teck-Peng Loh |
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| Affiliation: | a Division of Chemistry and Biological Chemistry, Nanyang Technological University, Singapore 637616, Singapore
b Department of Chemistry, 3 Science Drive 3, National University of Singapore, Singapore 117543, Singapore |
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| Abstract: | The ionic liquid [hmim][PF6] has been demonstrated as an efficient and environmentally-friendly reaction medium for the enantioselective allylation of aldehydes via a chiral indium(III) complex. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in moderate to good yields and enantioselectivities (upto 92% ee). |
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| Keywords: | Ionic liquid [hmim][PF6] Chiral indium complex Enantioselective allylation |
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