Catalytic aerobic photooxidation of primary benzylic amines using hindered acridinium salts |
| |
Authors: | Cyril Nicolas |
| |
Affiliation: | Département de Chimie Organique, Université de Genève, quai Ernest Ansermet 30, CH-1211 Genève-4, Switzerland |
| |
Abstract: | Hindered acridinium cations, simply prepared by the addition of primary amines to the known methylium tris(2,6-dimethoxyphenyl) cation, catalyze the aerobic photooxidation of primary benzyl amines into benzylimines. A mechanistic rationale for the electron-transfer process is proposed. |
| |
Keywords: | Amine Imine Photooxidation Acridinium Electron transfer |
本文献已被 ScienceDirect 等数据库收录! |
|