Catalytic aerobic photooxidation of primary benzylic amines using hindered acridinium salts |
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| Authors: | Cyril Nicolas |
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| Affiliation: | Département de Chimie Organique, Université de Genève, quai Ernest Ansermet 30, CH-1211 Genève-4, Switzerland |
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| Abstract: | Hindered acridinium cations, simply prepared by the addition of primary amines to the known methylium tris(2,6-dimethoxyphenyl) cation, catalyze the aerobic photooxidation of primary benzyl amines into benzylimines. A mechanistic rationale for the electron-transfer process is proposed. |
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| Keywords: | Amine Imine Photooxidation Acridinium Electron transfer |
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