Carboranylcorroles |
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| Authors: | Raymond J. Luguya |
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| Affiliation: | Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA |
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| Abstract: | The first syntheses of closo-carboranylcorroles (3, 4, and 11) have been achieved in a one-pot procedure from the condensation of pyrrole and carboranylbenzaldehydes, without the concomitant formation of the corresponding tetraarylporphyrins. The water-soluble nido-carboranylcorrole 9 was prepared from 7 in quantitative yield using tetrabutylammonium fluoride. The first X-ray molecular structure of a Cu(III) carboranylcorrole complex 7 is also presented. Carboranylcorroles absorb in the red region of the optical spectrum and should have potential application in both BNCT and PDT. |
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| Keywords: | Boron neutron capture Cancer treatment Carboranes Corroles Photodynamic therapy |
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