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Preparation of a Nafion-Teflon bimembrane-supported palladium catalyst and its use in the Heck reaction
Authors:Yangzhou Li  Fenggang Tao
Institution:Department of Chemistry, Fudan University, 200433 Shanghai, PR China
Abstract:A novel palladium catalyst supported on the Nafion membrane, reinforced with poly(tetrafluoroethylene) fiber, has been prepared. The catalyst exhibits high activity and stability in the Heck arylation reactions of aryl iodides with olefins and Sonogashira couplings with phenylacetylene, and can be readily recovered and reused twenty times without significant loss of activity.
Keywords:Palladium catalyst  Nafion film  Heck reaction  Sonogashira couplings
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