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Total synthesis of stevastelin B3 |
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| Authors: | Tushar Kanti Chakraborty Subhash Ghosh Pasunoori Laxman Shantanu Dutta Rajarshi Samanta |
| Institution: | Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| Abstract: | The total synthesis of stevastelin B3 was achieved using, as a key step, a method developed by us for the synthesis of 2-methyl-1,3-diols by Ti(III)-mediated diastereo- and regioselective opening of trisubstituted 2,3-epoxy alcohols, to carry out the stereoselective construction of its propionate-derived fatty acid segment. |
| Keywords: | Stevastelins Epoxide opening 2-Methyl-1 3-diol Immunosuppressants Depsipeptide |
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