Pd-catalyzed couplings of (α-fluoro)vinyl tris(trimethylsilyl)germanes |
| |
| Authors: | Zhizhong Wang |
| |
| Institution: | Department of Chemistry and Biochemistry, Florida International University, Miami, FL 33199, USA |
| |
| Abstract: | The (α-fluoro)vinyl tris(trimethylsilyl)germanes undergo Pd-catalyzed cross-couplings with aryl and alkenyl halides upon oxidative treatment with hydrogen peroxide under basic aqueous conditions to give access to fluoroalkenes and fluorodienes with retention of stereochemistry. |
| |
| Keywords: | Organogermanes Cross-coupling reactions Fluoroalkenes Fluorodienes |
| 本文献已被 ScienceDirect 等数据库收录！ |
