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A facile S-transalkylation of 2,2′-bipyridine alkyl sulfides—a new tool for the synthesis of annulated biheterocycles
Authors:Danuta Branowska  Andrzej Rykowski  Waldemar Wysocki
Institution:University of Podlasie, Department of Chemistry, ul. 3 Maja 54, 08-110 Siedlce, Poland
Abstract:A simple and efficient synthesis of annulated 2,2′-bipyridinium salts with attached dihydrothiazole or dihydro-1,3-thiazine rings has been developed through tandem S-transalkylation/intramolecular ring closure of 2,2′-bipyridine alkyl sulfides. The structures were confirmed by X-ray crystallographic analysis.
Keywords:S-Transalkylation  Annulated diquaternary 2  2&prime  -bipyridinium salts
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