β-Cyclodextrin promoted allylation of aldehydes with allyltributyltin under supramolecular catalysis in water |
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| Authors: | N. Srilakshmi Krishnaveni V. Pavan Kumar C. Suresh Reddy |
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| Affiliation: | a Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad 500 007, India
b Department of Chemistry, Sri Venkateswara University, Tirupati 517 502, India |
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| Abstract: | A novel and highly efficient allylation of aldehydes using allyltributyltin has been developed in aqueous medium catalyzed by β-cyclodextrin in the presence of HCl without any metal catalysts to afford the corresponding homoallylic alcohols in good yields. The β-cyclodextrin can be recovered and reused for a number of runs without significant loss of activity. |
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| Keywords: | Aldehydes Allylation Allyltributyltin β-Cyclodextrin HCl Water |
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