A simple route to novel functionalized tetrathiafulvalene vinylogues |
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| Authors: | Michel Guerro |
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| Institution: | Groupe Hétérochimie et Matériaux Electroactifs, Institut de Chimie de Rennes, SESO UMR-CNRS 6510, Université de Rennes 1, Bat 10A, 35042 Rennes cedex, France |
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| Abstract: | The synthesis and X-ray structural determination of vinylogous tetrathiafulvalenes (TTFV) bearing functional groups on the central conjugation are reported. An unexpected evolution of the bis hydroxymethyl TTFV leading to a derivative, which acts simultaneously as a diene and a dienophile in a Diels-Alder reaction is also described. |
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| Keywords: | Dithiafulvene Tetrathiafulvalene Oxidative coupling Diels-Alder |
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