Synthesis of phosphocyclic 2,2′,7,7′-tetrahydroxydinaphthylmethane derivatives |
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Authors: | Vera I Maslennikova Larisa K Vasyanina Wolf D Habicher |
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Institution: | a Department of Chemistry, Moscow Pedagogical State University, Nesvizhski per. 3, 119021 Moscow, Russia b Institute of Organic Chemistry, Dresden University of Technology, Mommsenstr. 13, D-01062 Dresden, Germany |
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Abstract: | Two types of phosphocyclic derivatives were synthesized by phosphorylation of 2,2′,7,7′-tetrahydroxydinaphthylmethane with triamidophosphites: triphosphorus containing compounds with a phosphocine ring and two acyclic diamidophosphite fragments, and tetraphosphorus-containing macrocycles with a 24-membered ring and two eight-membered phosphorus rings. It was shown that interaction of triphosphorus compounds with resorcinarene gives tetraphosphorus macrocycles. |
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Keywords: | 2 2&prime 7 7&prime -Tetrahydroxydinaphthylmethane Phosphorous triamides Phosphorylation Macrocycles Sulfurization Resorcinarene |
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