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Synthesis of 2,5-bis(2-aminothiazol-5-yl)-3,6-dichloro-1,4-benzoquinones
Authors:N G Batenko  R Valters  G Karlivans
Abstract:A series of 2-(2-aminothiazol-5-yl)-3,6-dichloro-5-diethylaminoethenyl-1,4-benzoquinones was synthesized from 2-(2-aminothiazol-5-yl)-3,5,6-trichloro-1,4-benzoquinones using acetaldehyde and diethylamine in toluene solution. Refluxing these compounds with substituted thioureas in acetonitrile in the presence of hydrochloric acid gives the corresponding 2,5-bis(2-aminothiazol-5-yl)-3,6-dichlorohydroquinones which can be oxidized to the target products with ferric chloride in aqueous DMF.Riga Technical University, Riga LV-1048, LatviaTranslated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 835–839, June, 2000
Keywords:2-(2-aminothiazol-5-yl)-3  6-dichloro-5-diethylaminoethenyl-1  4-benzoquinones  2-(2-aminothiazol-5-yl)-3  5  6-trichloro-1  4-benzoquinones  1  4-benzoquinones  2  5-bis(2-aminothiazol-5-yl)-3  6-dichloro-1  4-benzoquinones  thiazole  intramolecular charge transfer
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