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1D to 3D NMR study of microporous alumino‐phosphate AlPO4‐40 |
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| Authors: | Cláudia M. Morais Valérie Montouillout Michael Deschamps Dinu Iuga Franck Fayon Filipe A. A. Paz João Rocha Christian Fernandez Dominique Massiot |
| Affiliation: | 1. CEMHTI‐CNRS (UPR3079), 1D Ave Recherche Scientifique, 45071 Orléans cedex 2, France;2. LACCO‐CNRS (UMR6503), University of Poitiers, 40 Ave Recteur Pineau, 86022 Poitiers, France;3. Department of Chemistry, CICECO, University of Aveiro, 3810‐192 Aveiro, Portugal;4. LCS‐CNRS (UMR6506), ENSICAEN, 14050 Caen, France |
| Abstract: | From one‐ to two‐ and three‐dimensional MAS NMR solid‐state experiments involving 31P and 27Al, we show that the structure of microporous alumino‐phosphate AlPO4‐40 contains at least four times more sites than expected, and we attribute two types of AlIV sites. The newly described 27Al‐31P MQ‐HMQC opens new possibilities of describing details of three‐dimensional bounded networks. Copyright © 2009 John Wiley & Sons, Ltd. |
| Keywords: | NMR 31P 27Al alumino‐phosphate microporous materials |