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Photoinduced unzipping depolymerization of poly(olefin sulfone)s possessing photobase generator and base amplifier
Authors:Takeo Sasaki  Hiroaki Yaguchi
Affiliation:Department of Chemistry, Faculty of Science, Tokyo University of Science, 1‐3 Kagurazaka, Shinjuku‐ku, Tokyo 162‐8601, Japan
Abstract:The photoinduced depolymerization of poly(olefin sulfone)s was investigated. Poly(olefin sulfone)s possessing base‐amplifying groups were synthesized. A photobase‐generating compound was mixed with poly(olefin sulfone)s and irradiated with 254 nm UV light. The decomposition ratio was significantly enhanced in poly(olefin sulfone)s that possessed base‐amplifying groups. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 602–613, 2009
Keywords:base amplifier  degradation  lithography  photobase generator  photoinduced depolymerization  photoreactive effects  poly(olefin sulfone)s
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