Molecular orientation and mechanical anisotropy of polypropylene sheet containing N,N′‐dicyclohexyl‐2,6‐naphthalenedicarboxamide |
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Authors: | Yohei Uchiyama Shohei Iwasaki Chiaki Ueoka Takashi Fukui Kenzo Okamoto Masayuki Yamaguchi |
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Affiliation: | 1. School of Materials Science, Japan Advanced Institute of Science and Technology, 1‐1 Asahidai, Nomi, Ishikawa 923‐1292, Japan;2. New Japan Chemical Co., Ltd., 13 Yoshijima, Yaguracho, Fushimi, Kyoto 612‐8224, Japan |
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Abstract: | Effect of mixing and processing conditions at T‐die extrusion on the structure and mechanical properties is studied for isotactic polypropylene (PP) containing a small amount of β‐form nucleating agent, N,N′‐dicyclohexyl‐2,6‐naphthalenedicarboxamide. It is found that trigonal β crystals are predominantly formed in the extruded samples containing the nucleating agent irrespective of the mixing and processing conditions, leading to the marked mechanical toughness. On the contrary, the molecular orientation is significantly affected by the mixing and processing conditions. In particular, it should be noted that PP molecules in the extruded sheet which was mixed at high temperature (260 °C) and extruded at low temperature (200 °C) orient perpendicular to the applied flow direction. As a result, the sheet shows anomalous mechanical anisotropy. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 424–433, 2009 |
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Keywords: | poly(propylene) processing crystal structure mechanical properties orientation |
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