Copper (II) catalyzed homocoupling and heterocoupling of terminal alkynes |
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| Authors: | Maria Katrina Holganza Leslie Trigoura Suzanne Elfarra Yoona Seo Jeremy Oiler Yalan Xing |
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| Affiliation: | Department of Chemistry, William Paterson University, 300 Pompton Rd, Wayne, NJ 07470, United States |
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| Abstract: | Cu(OTf)2 catalyzed homo– and heterocoupling of aromatic and aliphatic terminal alkynes has been developed. Symmetric and unsymmetric 1,3-diynes have been synthesized in good yields under an aerobic condition in the presence of an organic base DBU. This reaction features mild conditions, a wide substrate scope, and excellent functional group compatibility. |
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| Keywords: | Homocoupling Heterocoupling Glaser reaction 1,3-Diynes |
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