Alternated π‐conjugated polymers based on a 1,2‐diiminocyclohexane chiral unit for nitroaromatics sensing |
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| Authors: | Simon Clavaguera Olivier J. Dautel Lionel Hairault Christophe Méthivier Pierre Montméat Eric Pasquinet Claire‐Marie Pradier Françoise Serein‐Spirau Salem Wakim Florian Veignal Joël J. E. Moreau Jean‐Pierre Lère‐Porte |
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| Affiliation: | 1. Institut Charles Gerhardt, UMR CNRS 5253, Equipe AM2N, Ecole Nationale Supérieure de Chimie de Montpellier, 8 Rue de l'Ecole Normale, 34296 Montpellier Cedex 05, France;2. CEA Le Ripault, BP 16, 37260 Monts, France;3. Laboratoire de Réactivité de Surface, UMR CNRS 7609, Université Pierre et Marie Curie, Case 178, 4 place Jussieu, 75252 Paris Cedex 05, France |
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| Abstract: | The detection of 2,4‐dinitrotoluene (DNT) by fluorescence quenching of a new class of polyimines consisting in π‐conjugated segments regularly alternated with chiral C2 symmetry units has been studied for solutions and thin films. Their photophysical properties and their sensitivity towards DNT detection has been compared to those of a small model molecule incorporating the same π‐conjugated segment. In solution, all the compounds exhibit the same photo‐physical properties and sensitivity towards DNT detection. In contrast, for thin films, better performances are observed in static conditions for this new class of polyimines compared to the small model molecule. It seems that C2 symmetry units prevent from the stacking of the π‐conjugated segments and provide in addition to high fluorescence signal an improved diffusion of the analyte inside the films. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4141–4149, 2009 |
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| Keywords: | chiral chiral polymers conjugated polymers fluorescence fluorescence nitroaromatics detection infrared spectroscopy polyimines sensors |
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