Thermal Analysis of the System Li2WO4-Li4P2O7-WO3 |
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| Authors: | Shurdumov B. K. Trunin A. S. Kuchukova M. A. |
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| Affiliation: | (1) Kabardino-Balkarian State University, Nalchik, Kabardino-Balkaria, Russia;(2) Samara State Technical University, Samara, Russia |
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| Abstract: | The system Li2WO4-Li4P2O7-WO3 in the range of WO3 contents of up to 60 mol % was studied by thermal analysis. In the examined range of the composition triangle, the crystallization fields of lithium tungstate and pyrophosphate, of congruently melting compound D (Li2WO4·WO3), and of incongruently melting compound D2 (2Li2WO4·Li4P2O7) were revealed, and the glass formation region was established. Low-melting compositions showing promise for synthesis of lithium-tungsten oxide bronzes were revealed. |
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