Stereoselective tricarbonylchromium migration reactions in axially chiral biaryl chromium complexes |
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| Affiliation: | 1. Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan;2. Kyoto Pharmaceutical University, Misasagi, Yamashina, Kyoto 640-8412, Japan |
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| Abstract: | The tricarbonylchromium group in thermodynamically unstable biaryl chromium complexes with a coordinating heteroatom at the side chain stereoselectively migrated to the other arene face to release the steric repulsion. |
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