Synthesis of laddersiloxanes by novel stereocontrolled approach |
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Institution: | Department of Applied Chemistry, Faculty of Engineering, Gunma University, Kiryu, Gunma 376-8515, Japan;Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8602 Japan |
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Abstract: | Three new pentacyclic laddersiloxanes were prepared by a new method utilizing single stereoisomer of disiloxanediol as a growing unit. Thus, one diastereomer of disiloxanediol, (RS)–i-PrPhSi(OH)]2O was isolated and treated with tetrachlorocyclotetrasiloxane, resulting in the formation of tricyclic laddersiloxanes with cis-Ph groups at terminals. All of the obtained isomers could be transformed into pentacyclic laddersiloxanes by dephenylchlorination followed by the reaction with (RS)–i-PrPhSi(OH)]2O. The structures of new tricyclic and pentacyclic laddersiloxanes were determined by X-ray crystallography. The thermogravity properties of laddersiloxanes depending on the molecular weight and structures were summarized. |
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