NHC-coordinated palladacycle catalyzed 1,2-addition of arylboronates to unactivated ketones |
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| Authors: | Ryo Akiyama Mariko Sugaya Hiraku Shinozaki |
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| Affiliation: | 1. Department of Materials Science and Engineering, Graduate School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, Japan;2. Department of Applied Chemistry, School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, Japan |
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| Abstract: | AbstractPalladium catalyzed intermolecular 1,2-addition of arylboronate to unactivated ketone was investigated. NHC-coordinated palladacycle 4c exhibited catalytic activity for the reactions and provided the corresponding tertiary alcohols and γ,γ-disubstituted γ-lactones in good to excellent yields. |
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| Keywords: | 1,2-Addition arylboronate palladacycle palladium catalysis unactivated ketone |
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