Effects of deuteration on the structure and magnetic properties of bis-quinolinium tetrabromidocuprate(II) dihydrate

Abstract

The partially d₆, 2] and fully d₂₀, 3] deuterated analogues of (QuinH)₂CuBr₄·2H₂O (d₀, 1) were prepared and their crystal structures were determined Quin = quinoline]. In both compounds, there is a clear disorder in the positions of the bromide ions which was resolved. This led to a reexamination of the structure of the parent, fully protonated compound (1) where a small percentage of previously unrecognized disorder was also observed and the structure rerefined. Variable temperature magnetization measurements over the range 1.8–310?K indicate that all three materials behave as magnetically well-isolated layers that can be evaluated using the 2D-quantum Heisenberg antiferromagnetic model. Final fitting results for the partially (J = ?5.96(5) K) and fully (J = ?5.77(2) K) deuterated compounds indicate slightly weaker exchange compared to the protonated compound (J = ?6.17(3) K), likely as a result of the increased disorder in the deuterated phases.