Composition of hydrofullerene mixtures produced by C(60) reaction with hydrogen gas revealed by high-resolution mass spectrometry |
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Authors: | Talyzin Alexander V Tsybin Yury O Schaub Tanner M Mauron Philippe Shulga Yury M Züttel Andreas Sundqvist Bertil Marshall Alan G |
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Institution: | Department of Physics, Ume? University, 901 87 Ume?, Sweden, Ion Cyclotron Resonance Program, National High Magnetic Field Laboratory, Tallahassee, Florida 32310-4005, USA. alexandr.talyzin@physics.umu.se |
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Abstract: | Complex solid hydrofulleride mixtures were synthesized by prolonged hydrogenation of C(60) at 120 bar hydrogen pressure, 673 K temperature, and different reaction periods. The high degree of hydrogenation was confirmed by infrared spectroscopy and X-ray diffraction. The identity of hydrogenation products was determined by high-resolution field desorption/ionization Fourier transform ion cyclotron resonance mass spectrometry. Despite partial gas-phase fragmentation of hydrofullerene ions during mass analysis, the data suggest that the synthesized mixtures consist of mostly C(58-60)H(x) hydrofullerenes. Increasing the duration of hydrogenation results in synthesis of C(59)H(x) and C(58)H(x) as major products. Possible hydrofullerene fragmentation pathways during both material synthesis and mass spectrometric analysis are discussed. Gas-phase fragmentation in the mass spectrometer arises from hydrofullerene ions C(60)H(x)(+) with x > 40 and C(59)H(44)(+) with drastically decreased molecular stability relative to the known C(60)H(36). |
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