Kationische cyclisierung von (Z)-und (E)-1,3-dimethyl-2-(3-hexenyl)-2-cyclohexenol |
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Authors: | E -J Brunke F -J Hammerschmidt H Struwe |
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Institution: | DRAGOCO GmbH, Forschungsabteilung, D-3450 Holzminden, Germany |
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Abstract: | The cationic cyclization of the carbinol (Z) occurred stereoselectively and resulted in a mixture of the hydrindane and the octalin , both with configuration of side chain and angular methyl group. Cyclization of (E) yielded in and , both with -configuration. The structure of , was proved by transformation to the diketones ,. |
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Keywords: | |
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