Syntheses and crystal structures of triorganotin(IV) complexes based on mixed ligands of 2,4,5-trifluoro-3-methoxybenzoic acid and 4,4′-bipy |
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| Authors: | Chun-Lin Ma Ya-Wen Han Ru-Fen Zhang |
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| Institution: | (1) Department of Chemistry, Liaocheng University, Liaocheng, 252059, P.R. China;(2) Taishan University, Taian, 271021, P.R. China |
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| Abstract: | Four new complexes have been synthesized based on the 2,4,5-trifluoro-3-methoxybenzoic acid and 4,4′-bipy of the type R3Sn(OOCC6HF3OCH3)]2·(4,4′-bpy). All complexes were characterized by elemental, IR, 1H, 13C and 119Sn NMR spectra analyses. Complexes 1 and 4 were also characterized by X-ray crystallography. Crystal structures of 1 and 4 show that the coordination number of tin atom is five and the 2D network is connected by intermolecular C–H···O interactions. |
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| Keywords: | 2 4 5-Trifluoro-3-methoxybenzoic acid 4 4′ -Bipy Organotin(IV) 2D network |
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