| 过渡金属硫簇的几种簇骼转化反应 |
| |
| 引用本文： | 刘秋田,康北笙,陈昌能,杨瑜,陈学太,卢嘉锡. 过渡金属硫簇的几种簇骼转化反应[J]. 结构化学, 1994, 0(3) |
| |
| 作者姓名： | 刘秋田 康北笙 陈昌能 杨瑜 陈学太 卢嘉锡 |
| |
| 作者单位： | 中国科学院福建物质结构研究所 |
| |
| 基金项目： | 国家攀登计划资助,国家自然科学基金 |
| |
| 摘 要： | 报道了过渡金属硫簇化合物的几种簇骼转化反应，即三核链状簇的转化；双核配合物的组合；Ｍｏ２Ｆｅ７Ｓ８和Ｍｏ２Ｆｅ６Ｓ８两种双立方烷的关联；Ｆｅ４Ｓ４立方烷簇向篮状簇的转化；簇降解以及簇骼原子置换反应等。探讨了配体及氧化还原条件对簇骼转化反应的影响。
|
| 关 键 词： | 簇骼转化，过渡金属原子簇，金属硫簇 |
Some Types of Skeletal Conversions in Transition Metal Sulfur Clusters |
| |
| Liu Qiu-Tian,Kang Bei-Sheng ,Chen Chang-Neng,Yang Yu,Chen Xue-Tai,Lu Jia-Xi. Some Types of Skeletal Conversions in Transition Metal Sulfur Clusters[J]. Chinese Journal of Structural Chemistry, 1994, 0(3) |
| |
| Authors: | Liu Qiu-Tian Kang Bei-Sheng Chen Chang-Neng Yang Yu Chen Xue-Tai Lu Jia-Xi |
| |
| Abstract: | Some types of skeletal conversions in transition metal sulfur clusters are reported in this paper.A trinuclear linear cluster Fe(DMF)6[(FeCl2)2MoS4] underwent three modes of skeletal conversions in the presence of various ligands,bidentate R2dtc- leading to a single MoFe3S4 cubane-like cluster, monodentate PhS-leading to double cubane cluster,and the mixed ligands(R2dtc- and PhS-) leading to a tetranuclear linear Mo- Fe- Fe- Mo cluster and a Fe4S4cubane-like cluster.Other skeletal conversions in the metal-sulfur clusters include reductive combinations of dinuclear complexes,degradations of tri- and tetrnuclear clusters,the conversion of Fe4S4 cubane-like cluster into a Fe6S4(μ-SPh) backet cluster,the relative conversion between both double cubanes Mo2Fe7S8 and Mo2Fe6S8,and displacement of skeletal atoms in [Mo3S4(H2O)9]4+.The influences of ligands,redox conditions and steric effect on the skeletal conversions are also discussed. |
| |
| Keywords: | skeletal conversion transition metal cluster metal-sulfur cluster |
| 本文献已被 CNKI 等数据库收录！ |
|
