Reactions of Sulfenyl,Sulfinyl, and Sulfonyl Halides with Conjugated Dienes and Enynes. Synthesis of Unsaturated Sulfides,Sulfoxides, and Sulfones |
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Authors: | Stadnichuk M D |
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Institution: | (1) St. Petersburg State Institute of Technology, St. Petersburg, Russia |
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Abstract: | The reactivities of sulfenyl, sulfinyl, sulfonyl halides in additions to conjugated dienes'enynes, and their derivatives are compared. Despite the fact that all these reactions involve cleavage offormally similar S-Cl bonds, the addition direction and rate depend on the structure of the reactants (dienes and enynes; organosulfur acid chlorides). |
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