Structural and spectral studies of a new copper(II) complex with a tridentate thiosemicarbazone ligand |
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| Authors: | Soma Sen Shyamapada Shit Samiran Mitra Stuart R. Batten |
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| Affiliation: | (1) Department of Chemistry, Jadavpur University, Kolkata, 700 032, West Bengal, India;(2) Department of Chemistry, Monash University, 3800 Victoria, Australia |
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| Abstract: | The reaction of copper(II) chloride dihydrate with 2-hydroxy-3-methoxybenzaldehydethiosemicarbazone (HL) ligand in a 1:1 ratio forms the complex [Cu(L)(Cl)] · H2O. The complex is characterized by spectroscopic, electrochemical, and thermal analysis. X-ray crystallographic analysis reveals that the central copper atom displays the distorted square planar geometry. The water molecule present in the lattice participates in a strong hydrogen bonding network, which leads to a 2D supramolecular arrangement. |
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| Keywords: | Cu(II) Thiosemicarbazone ligand X-ray structure Spectroscopic Electrochemical Thermal analysis |
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