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直线群及其在聚合物结构中的应用
引用本文:安宝珠.直线群及其在聚合物结构中的应用[J].高分子通报,1991(2).
作者姓名:安宝珠
作者单位:中国科技大学研究生院 北京
摘    要:对聚合物晶体中各种高分子链的构象进行了研究,找出了它们的三维对称性,并用直线群来表征。在此基础上,讨论了分子链在空间群中排布的规律性,即在空间群中高分子链的对称性与所在位置的对称性相呼应。并利用直线群讨论了有序-无序高分子链所在空间群转变的规律性。

关 键 词:直线群  对称性  聚合物结构  晶体结构  空间群  有序-无序转变

Characteristics of Macromolecular Chains by Line Groups and the Applications of Line Groups to Crystal Structures of Polymers
An Baozhu.Characteristics of Macromolecular Chains by Line Groups and the Applications of Line Groups to Crystal Structures of Polymers[J].Polymer Bulletin,1991(2).
Authors:An Baozhu
Abstract:The three-dimensional symmetry of a macromolecular chain was characterized by the line group. Regularities of packing of macromolecular chains in a space group were shown. That is in a space group the symmetries of a macromolecular chain have to correspond with the symmetries of the position occupied by the chain. Order-disorder transitions in polymer crystals were studied by means of line groups.
Keywords:Line group  Symmetry  Polymer  Crystal structure  Space group  Order-disorder transitions
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