Suzuki cross-coupling/reductive debenzyloxycarbonylation sequence for the syntheses of [c]annulated isoquinolines: application for the syntheses of pancratistatin-like isoquinolines |
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| Authors: | Pandey Ganesh Balakrishnan Madhesan |
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| Institution: | Division of Organic Chemistry, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008, India. gp.pandey@ncl.res.in |
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| Abstract: | A two-step strategy involving Suzuki cross-coupling of boronic acids with a diverse array of alpha-iodoenones followed by hydrogenation is developed for the construction of c]annulated isoquinolines. This mild and efficient procedure is also applied to the synthesis of highly oxygenated isoquinolines. |
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