Nickel-catalyzed borylative ring-opening reaction of vinylcyclopropanes with bis(pinacolato)diboron yielding allylic boronates |
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| Authors: | Sumida Yuto Yorimitsu Hideki Oshima Koichiro |
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| Institution: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. |
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| Abstract: | Vinylcyclopropanes bearing one or two electron-withdrawing groups on the cyclopropane ring undergo nickel-catalyzed borylative ring opening with bis(pinacolato)diboron to yield allylic boronates. The reaction proceeded with high E selectivity. |
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